| Source | UN (World Urbanization Prospects 2018) |
| Date | 01 Apr 2024 |
| Code | City | Population | Share (%) | Rank | Change | |||
|---|---|---|---|---|---|---|---|---|
| 2023 | 2024 | Ukraine | World | Population | (%) | |||
| Kyiv | Kyiv (Kiev) | 3,016,789 | 3,020,228 | 7.96 | 1 | 182 | 3,439 | 0.11 |
| Khar | Kharkiv | 1,421,052 | 1,418,978 | 3.74 | 2 | 419 | -2,074 | -0.15 |
| Odes | Odesa | 1,007,716 | 1,007,596 | 2.66 | 3 | 633 | -120 | -0.01 |
| Dnip | Dnipro | 941,586 | 936,766 | 2.47 | 4 | 684 | -4,820 | -0.51 |
| Done | Donetsk | 887,716 | 882,209 | 2.33 | 5 | 722 | -5,507 | -0.62 |
| Zapo | Zaporizhzhya | 724,240 | 720,595 | 1.90 | 6 | 891 | -3,645 | -0.50 |
| Lviv | Lviv | 720,468 | 719,663 | 1.90 | 7 | 894 | -805 | -0.11 |
| Kryv | Kryvyi Rih | 604,258 | 599,758 | 1.58 | 8 | 1070 | -4,500 | -0.74 |
| Myko | Mykolaiv | 479,685 | 478,230 | 1.26 | 9 | 1337 | -1,455 | -0.30 |
| Mari | Mariupol | 431,298 | 428,766 | 1.13 | 10 | 1488 | -2,532 | -0.59 |
| Seva | Sevastopol | 400,613 | 401,510 | 1.06 | 11 | 1572 | 897 | 0.22 |
| Luha | Luhansk | 392,295 | 389,333 | 1.03 | 12 | 1617 | -2,962 | -0.76 |
| Vinn | Vinnitsa | 375,805 | 375,606 | 0.990 | 13 | 1664 | -199 | -0.05 |
| Simf | Simferopol | 339,863 | 339,826 | 0.896 | 14 | 1794 | -37 | -0.01 |
| Maki | Makiivka | 331,799 | 329,621 | 0.869 | 15 | 1822 | -2,178 | -0.66 |